Which processes play a role in the development of MIC corrosion?
When oxygen is not available, certain bacteria can use sulphate as “alternative breathing”, converting it to sulphide (usually hydrogen sulphide). We call this sulfate reduction. There are two routes for sulphate reduction, involving bacteria. The best known is the reduction route in which bacteria use chemical compounds from organic material and produce H2S. In the second route, the bacteria extract electrons from the metal surface. The bacteria dissolve iron and produce sulphide. This leads to pit corrosion, which is very characteristic for MIC corrosion. A well-designed cathodic protection system, is an effective way to prevent the growth of these bacteria on the metal surface, but cannot prevent the formation of H2S.
H2S formation, recognizable by the smell of rotten eggs, is highly undesirable because it is corrosive and can affect the metal pipeline. But that is not the only problem: it is also toxic and explosive. That is why we have investigated various ways to prevent the production of hydrogen sulphide.